You can create a rule for an application only if the application is already in the application list. If this application is not in the list, you should Add it to the list.
To create a rule for an application using presets:
1. Select Options
2. Select Application
3. Highlight the application
4. Click Edit
5. On the drop down list, select Create Rules Using Presets...
6. Select the rules of the preset you want to add to this application.
You can create a rule only for the applications that have Partially allowed status.