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- Xref: sparky talk.environment:5243 sci.energy:6440
- Newsgroups: talk.environment,sci.energy
- Path: sparky!uunet!usc!rpi!batcomputer!cornell!rochester!dietz
- From: dietz@cs.rochester.edu (Paul Dietz)
- Subject: Re: NEWS: UN Convenes Special Meeting on Nuclear Transports
- Message-ID: <1992Dec24.135017.2606@cs.rochester.edu>
- Organization: University of Rochester
- References: <JMC.92Dec14161859@SAIL.Stanford.EDU> <1992Dec16.054346.7830@scammell.ecos.tne.oz.au> <1981@spam.ua.oz>
- Date: Thu, 24 Dec 1992 13:50:17 GMT
- Lines: 37
-
- In article <1981@spam.ua.oz> jaskew@spam.ua.oz (Joseph Askew) writes:
-
- >>Rather than tell us it is a lie, back up your claim. What do the processing
- >>plants do?
- >
- >Reprocessing plants remove the Plutonium and unused Uranium from the left
- >over fuel. Essentially they dissolve the rods in a Nitric acid solution.
- >The aqueous solution is mixed with a chemical which has a higher affinity
- >for the Pu and U than the aqueous solution. ...
-
-
- There is considerable interest (including in Japan) in a new
- reprocessing technology that is considerably different from this. The
- new process, being worked on at Argonne National Lab, is a
- pyro(electro)chemical process.
-
- In this process, oxide fuels are reduced to metals by reaction with
- calcium metal (metal fuels are just cut up). The fragments are
- dissolved into a molten chloride eutectic (potassium and lithium
- chloride, I think). Electromigration separates out the uranium (onto
- an iron cathode) and a uranium/plutonium(+TRU) mix (into a molten
- cadmium cathode). The U/Pu ratio is controlled by adjusting how much
- uranium is removed in the previous stage The lanthanides and other
- fission products stay in the electrolyte (or don't dissolve). After
- 20 or so cycles, the electrolyte is removed and replaced with a fresh
- mixture.
-
- This process does not highly purify the plutonium -- it still contains
- appreciable fission products. Although not enough to be significant
- in the operation of a reactor, these products would make the fuel
- difficult to divert for clandestine use in nuclear weapons. It is
- also much more compact than the nitric-acid based scheme, and is
- intended to be used on-site, rather than at a remote reprocessing
- plant.
-
- Paul F. Dietz
- dietz@cs.rochester.edu
-