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- From: ames!FNALD.FNAL.GOV!DROEGE
- Subject: Status #2 Cell 4A3
- Message-ID: <921224131545.20c03af9@FNALD.FNAL.GOV>
- Sender: scott@zorch.SF-Bay.ORG (Scott Hazen Mueller)
- Reply-To: ames!FNALD.FNAL.GOV!DROEGE
- Organization: Sci.physics.fusion/Mail Gateway
- Date: Mon, 28 Dec 1992 17:56:55 GMT
- Lines: 48
-
- When we first tried to ramp up cell 4A3, nothing happened with the gas. After
- a struggle, it was determined (at 3 AM) that there was a gas leak. The new
- servo switch was balanced so well that it just sat at one spot with a leak.
- Will have to set it for a positive pressure for the next run to more quickly
- expose leaks. What wonders Tom Edison could have performed had he had 5
- minute epoxy! But the result of all this struggle was that there was likely
- 0.05 to 0.1 D/Pd absorption.
-
- The cell was then run reverse for 24 hours with only a couple of cc of gas
- evolution. We are not sure that this will remove absorbed gas, especially at
- the very low reverse current that we used.
-
- We then ramped up cell 4A3 at 1 ma per sq cm per hour. After 17 hours it hit
- the limit at about 0.8 D/Pd. At this point the current density was 17 ma per
- sq cm. After another half day with the slow cell current ramp still on, and
- little or no change in loading, we increased the ramp to 50 ma per sq cm per
- hour. This caused an immediate indication of increased loading. Eventually
- we appeared to get to 2 D/Pd.
-
- I say "appeared" since what was likely happening was that the catalyst was
- becoming less efficient. What is required to explain the result is that the
- catalyst needs higher and higher concentrations of D2 and O2 to operate as the
- watts per unit surface area increase. But the numbers are not large, the
- catalyst efficiency has only to change from 100% efficient to 90% efficient to
- get my result. In other words, the catalyst was failing, but was still
- converting most of the evolved gas.
-
- By the time we got to 2 D/Pd (remember we measure excess gas - presumed oxygen
- from the D2 that was absorbed) the excess gas was accelerating even faster
- than the current was increasing so it was suspicious. We then backed down the
- current and the excess gas decreased, indicating that there really was un-
- recombined D2 and O2 in the cell (or that the cathode was outgassing - just
- can't tell). Still we could only get it down to an indicated 1.6 D/Pd no
- matter what we did, including turning up the heat on the catalyst. (Except
- for the resulting transient, my computer keeps track of all this so that such
- things can be done while still maintaining an energy balance.)
-
- So it is a tough business. I think the 0.8 number is conservative, especially
- in view of the unknown amount of charging when the cell was leaking. This was
- also measured at very low current and with the catalyst heater on to insure
- that it would be working. But I just don't know about the larger numbers. We
- really need to measure the gas and the cathode resistance at the same time and
- make comparisons, but it is so hard to get all those leads into the cell!
-
- Happy Christmas to all, and to all a Good Night!
-
- Tom Droege
-
-